Title page for ETD etd-01252012-185606


Type of Document Dissertation
Author Zhang, Bin
Author's Email Address zhangb81@vt.edu
URN etd-01252012-185606
Title Synthesis and Characterization of trans-1,4-Cyclohexylene Ring Containing Poly(arylene ether sulfone)s
Degree PhD
Department Chemistry
Advisory Committee
Advisor Name Title
Turner, S. Richard Committee Chair
Deck, Paul A. Committee Member
Long, Timothy E. Committee Member
Marand, Herv L. Committee Member
Riffle, Judy S. Committee Member
Keywords
  • poly(arylene ether sulfone)s
  • trans-1,4-cyclohexylene ring
  • polysulfone-polyester
  • multiblock copolymers
  • relaxation
  • mechanical properties
  • structure-property relationship
Date of Defense 2012-01-13
Availability unrestricted
Abstract
Poly(arylene ether sulfone)s (PAES) are important commercial polymers and have been extensively studied due to their excellent thermal and mechanical properties. However, some applications are still limited when good solvent resistance and low thermal expansion coefficient are required. There has been a continuous interest in developing new PAES based on new monomers or polymer modifications to obtain new properties or to enhance existing properties. In this dissertation, the synthesis, characterization and structure-property relationship of new 1,4-cyclohexylene ring containing PAESs were comprehensively studied. Different polymerization techniques were used to synthesize polymers with different segmental lengths.

The monomer, 4,4'-[trans-1,4-cyclohexanebis(methylene)] bisphenol (CMB), was synthesized and fully characterized. Based on 4,4’-dihydroxy-p-terphenyl (DHTP), 4,4’-dihydroxybiphenyl (DHBP) and the CMB monomer, homopolymer and random copolymers of PAES were prepared with high molecular weights and high glass transition temperatures. Dynamic mechanical analysis (DMA) on these polymers showed multiple sub-Tg relaxations. A large increase in the ultimate elongation was obtained with the CMB and DHTP containing sample, which could be due to the strong sub-Tg relaxations observed from the DMA results.

A series of four acid chloride monomers were synthesized and polymerized with phenol terminated PAES oligomers. Solution polymerization and pseudo-interfacial polymerization techniques were used to prepare both bisphenol-A (bis-A) based and DHBP based PAES oligomers. With the incorporation of the trans-1,4-cyclohexylene units, decreases in the glass transition temperatures were observed from both the bis-A based and the DHBP based polymers. However, melting transitions were only observed in the DHBP based trans-1,4-cyclohexylene containing PAESs. Crystallinity was confirmed by differential scanning calorimetry (DSC) and wide angle X-ray diffraction (WAXD). A mechanical property study of the high molecular weight trans-1,4-cyclohexylene containing polymer samples showed moderate ultimate elongation enhancements.

A series of PAES-polyester multiblock copolymers were synthesized with both solution method and melt polymerization. In the solution method, phenol terminated PAES oligomers and the acid chloride terminated poly(1,4-cyclohexylenedimethylene terephthalate) (PCT) oligomers were presynthesized and coupled in solution. The molecular weights of the polymer products obtained from the solution method were limited by solubility issues. Melt phase polymerization was employed to obtain high molecular weight polymers. Hydroxy ethoxy terminated PAES oligomers were synthesized and polymerized with 1,4-cyclohexanedimethanol (CHDM) and dimethyl terephthalate (DMT) in the melt. Polymers with high molecular weights were obtained. Tensile test results suggested that the mechanical properties of these polymers were dominated by the PAES components with polyester contents up to 20 wt%. Melting transitions were observed from polymers with higher polyester contents, and these polymers exhibited limited solubility in common organic solvents.

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