

Type of Document Dissertation Author Triampo, Wannapong Author's Email Address wtriampo@yahoo.com URN etd-04102001-113110 Title Non-Equilibrium Disordering Processes In binary Systems Due to an Active Agent Degree PhD Department Physics Advisory Committee
Advisor Name Title Schmittmann, Beate Committee Chair Heflin, James R. Committee Member Ritter, Alfred L. Committee Member Tauber, Uwe C. Committee Member Zia, Royce K. P. Committee Member Keywords
- Vacancy-mediated dynamics
- Non-equilibrium processes
- Monte Carlo
- Brownian motion
- Dynamic scaling
- Random walk
- Disordering process
- Mean-field theory
- Ising model
- Data corruption
Date of Defense 2001-04-10 Availability unrestricted Abstract In this thesis, we study the kinetic disordering of systemsinteracting with an agent or a walker. Our studies divide naturally into two
classes: for the first, the dynamics of the walker conserves the total
magnetization of the system, for the second, it does not. These distinct
dynamics are investigated in part I and II respectively.
In part I, we investigate the disordering of an initially
phase-segregated binary alloy due to a highly mobile vacancy which exchanges
with the alloy atoms. This dynamics clearly conserves the total
magnetization. We distinguish three versions of dynamic rules for the
vacancy motion, namely a pure random walk , an ``active' and a biased walk.
For the random walk case, we review and reproduce earlier work by Z.
Toroczkai et. al.,~cite{TKSZ} which will serve as our base-line. To test
the robustness of these findings and to make our model more accessible to
experimental studies, we investigated the effects of finite temperatures
(``active walks') as well as external fields (biased walks). To monitor the
disordering process, we define a suitable disorder parameter, namely the
number of broken bonds, which we study as a function of time, system size
and vacancy number. Using Monte Carlo simulations and a coarse-grained field
theory, we observe that the disordering process exhibits three well
separated temporal regimes. We show that the later stages exhibit dynamic
scaling, characterized by a set of exponents and scaling functions. For the
random and the biased case, these exponents and scaling functions are
computed analytically in excellent agreement with the simulation results.
The exponents are remarkably universal. We conclude this part with some
comments on the early stage, the interfacial roughness and other related
features.
In part II, we introduce a model of binary data corruption induced
by a Brownian agent or random walker. Here, the magnetization is not
conserved, being related to the density of corrupted bits }$ ho ${small .}
{small Using both continuum theory and computer simulations, we study the
average density of corrupted bits, and the
associated density-density correlation function, as well as several other
related quantities. In the second half, we
extend our investigations in three main directions which allow us to make
closer contact with real binary systems. These are i) a detailed analysis of
two dimensions, ii) the case of competing agents, and iii) the cases of
asymmetric and quenched random couplings. Our analytic results are in good
agreement with simulation results. The remarkable finding of this study is
the robustness of the phenomenological model which provides us with the tool,
continuum theory, to understand the nature of such a simple model.
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