Title page for ETD etd-04142009-040728


Type of Document Master's Thesis
Author Lovelace, Thomas Claiborne
URN etd-04142009-040728
Title Synthesis of ipomeamarone via the [2+3] dihydrofuran annulation
Degree Master of Science
Department Chemistry
Advisory Committee
Advisor Name Title
Hudlicky, Tomas Committee Chair
Merola, Joseph S. Committee Member
Tanko, James M. Committee Member
Keywords
  • Ipomeamarone
Date of Defense 1990-03-02
Availability restricted
Abstract

The synthesis of several dihydrofurans of type 179 was accomplished by the flash vacuum pyrolysis of vinyloxiranes of type 178 obtained from the addition of the dienolate of ethyl-2-bromocrotonate (177) to various aldehydes (176). Thus, dihydrofurans were prepared from aldehydes in an overall intermolecular [2+3] dihydrofuran annulation.

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