Title page for ETD etd-04142011-141440


Type of Document Dissertation
Author Thridandapani, Raghunath Rao
Author's Email Address rrt9001@vt.edu
URN etd-04142011-141440
Title The Effect of Microwave Energy on Sintering
Degree PhD
Department Materials Science and Engineering
Advisory Committee
Advisor Name Title
Clark, David E. Committee Chair
Hendricks, Robert W. Committee Member
Lu, Guo-Quan Committee Member
Pickrell, Gary R. Committee Member
Keywords
  • Microwaves
  • Sintering
  • Activation Energy
  • Zirconia
Date of Defense 2011-04-01
Availability unrestricted
Abstract
Spent Nuclear Fuel (SNF) is a by-product of existing nuclear reactors; SNF consists of long-lived radioactive actinides which have an average half-life of several thousand years (e.g. Plutonium-239 with a half-life of 24,000 years, and Americium-243 with a half-life of 7,360 years). Several multinational organizations are making an attempt to extract the energetic value out of these nuclear stockpiles in order to minimize the risk of nuclear proliferation and reduce waste volume. The Inert Matrix Fuel (IMF) concept is being considered as an option to reuse the radioactive actinides present in spent nuclear fuel by means of a transmutation process. Due to the volatile nature of these radioactive actinides, it is expected that the high-temperature conventional processing of IMFs will result in a significant loss of material.

This study investigates microwave sintering of inert matrix material (excluding actinide fuel) as an alternative route to conventional processing. It was observed that microwave sintering showed a reduction of 300°C in temperature required for full densification when compared to conventional sintering. The reduction in sintering temperatures did not show any significant variation in the resulting properties (hardness and grain size). While these results satisfy the need for the application, it is important to understand why microwaves enhance the sintering phenomena.

It is speculated (by many researchers) that the electric field associated with microwave energy is enhancing flux leading to accelerated densification during microwave sintering. This study has observed a decrease in the activation energy (for sintering 8YZ) with the increase in the magnitude of the applied electric field.

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