Title page for ETD etd-04232004-091718


Type of Document Dissertation
Author McCann, Martha Mary
Author's Email Address mamccann@vt.edu
URN etd-04232004-091718
Title Nanoindentation of Gold Single Crystals
Degree PhD
Department Materials Science and Engineering
Advisory Committee
Advisor Name Title
Corcoran, Sean Gerald Committee Chair
Aning, Alexander O. Committee Member
Farkas, Diana Committee Member
Kampe, Stephen L. Committee Member
Reynolds, William T. Jr. Committee Member
Keywords
  • Surface Structure
  • Electrochemical Modification
  • Yield Variability
  • Nanoindentation
  • Hardness Variability
  • Gold
Date of Defense 2004-03-29
Availability unrestricted
Abstract
Nanoindentation is an increasingly used tool to investigate the mechanical properties of very small volumes of material. Gold single crystals were chosen as a model system for surface modification studies, because of the electrochemical advantages and the simple structure of the material. Experiments on these samples displayed a spectrum of residual deformation, with measured hardness values on the same surface differing by over a factor of two. The yield point also exhibited considerable variation, but the depth of penetration was independent of this elastic–plastic transition. The onset of plastic deformation in these tests is observed at stress levels on the order of the theoretical yield strength. There are a limited number of defects in a single crystal specimen of gold, especially on the length scale required to influence nearly every indentation experiment. A test matrix was designed to change the concentrations of possible defects in a sample (dislocations, vacancies, and structural features), by altering some of the surface preparation parameters. The results of these experiments were extremely consistent. Observed trends within the matrix, combined with the observations of reduced hardness and earlier plasticity when compared to the preliminary testing, indicate a decline in the structural continuity of the sample. This is surprising considering the extensive material removal and thermal history of some of these surfaces. There is no indication of a cause for the dramatic inconsistencies in mechanical properties observed in preliminary testing, but a consistent surface enables the study of intentional modifications. Changes in contact area that were undetectable in preliminary results now demonstrate predictable shifts in hardness values. The deposition of a single monolayer of gold oxide raised the average load at yield by a factor of three and increased the hardness by over 26%. Attributing this change to the oxide is corroborated by the reduction of hardness when the oxide is stripped. Similar behavior is observed when a lead monolayer is deposited and tested ex-situ. It is surprising that layers <0.5 nm in thickness would have such a dramatic influence on indentation tests at least 35 nm deep. This indicates that no surface layer can be ignored at this scale. These experiments demonstrate that there is still much to be learned about nanoscale deformation mechanisms.
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