Title page for ETD etd-11152013-040335


Type of Document Master's Thesis
Author Schnitzer, Jill
URN etd-11152013-040335
Title Liquid phase hydroformylation by zeolite supported rhodium
Degree Master of Science
Department Chemical Engineering
Advisory Committee
Advisor Name Title
Mark E. Davis Committee Chair
Brian E. Hanson Committee Member
Felix Sebba Committee Member
Keywords
  • Catalysis
Date of Defense 1985-12-05
Availability restricted
Abstract
The purpose of this research was to directly compare the behavior of zeolites containing rhodium with that of homogeneous

rhodium species as catalysts for liquid phase

hydroformylation of 1-hexene in order to study the effects of zeolite immobilization. NaX zeolite was cation exchanged with several rhodium salts and used as hydroformylation catalysts at 50°C and l25°C in the presence of: triphenylphosphine (PPh3), dimethylphenylphosphine (PMe2Ph),

and the poison for zeolite surface and solution rhodium: triphenylmethylmercaptan (Ph3CSH). The results of these experiments were compared with those of several homogeneous catalysts under similar conditions.

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