Type of Document	Dissertation
Author	Carver, David Reginald
URN	etd-11302012-040014
Title	The SRN1 reactivity of selected aromatic diazines
Degree	PhD
Department	Chemistry
Advisory Committee	Advisor Name Title Wolfe, James F. Committee Chair Bell, Harold M. Committee Member Hudlicky, M. Committee Member Sanzone, George Committee Member Taylor, Larry T. Committee Member
Keywords	Substitution reactions
Date of Defense	1979-08-05
Availability	restricted
Abstract The scope and limitations of aromatic diazines undergoing nucleophilic substitution reactions occurring via a radical-chain (SRN1) mechanism were investigated. The study was conducted on a series of mono- and dihalogenated aromatic diazines interacting with various ketone enolates in ammonia. Results indicate that this previously unrecognized reaction pathway in these nitrogen heterocycles is easily obtained and should prove of great synthetic utility in preparation of substituted diazines.
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