Title page for ETD etd-71498-12035


Type of Document Master's Thesis
Author Bi, Feng Jr.
Author's Email Address fbi@vt.edu
URN etd-71498-12035
Title The Asymmetric Synthesis Of The C1'-C10' Portion Of Pamamycin-621A
Degree Master of Science
Department Chemistry
Advisory Committee
Advisor Name Title
Ducker, William A.
Tanko, James M.
Calter, Michael A. Committee Chair
Keywords
  • Pamamycin
  • Lower Portion
  • Synthesis
  • Ketene
Date of Defense 1998-08-04
Availability unrestricted
Abstract
The Asymmetric Synthesis of the C1'-C10' Portion of Pamamycin-621A

Feng Bi

(ABSTRACT)

This thesis describes the synthesis of the C1'-C10' portion 72 of the pamamycin-621A using a cuprate conjugate addition to join enone fragment 52 and organostannane fragment 64a. Fragments 52 and 64a were both synthesized from (S)-methylketene dimer 51.

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